Portrait of John Bardeen

Adapted from ⁠an image by Nobel foundation (public domain), via Wikimedia Commons.

1908–1991

John Bardeen

The only person to win the Nobel Prize in Physics twice: for the transistor, and for explaining superconductivity.

Element

32GeGermanium
1947

At Bell Labs, John Bardeen and Walter Brattain pressed two gold contacts onto a slab of germanium and amplified a signal. The transistor went on to replace the vacuum tube.

Bardeen's transistor depended on germanium with a trace of other atoms added. Dope a semiconductor and watch it conduct.

Semiconductors

Doping: make it conduct

Pure germanium barely conducts: every outer electron is locked in a bond. Swap in a few atoms of another element, called doping, and it starts to conduct. Every computer chip is built this way.

GeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGeGe
  • Free electron
  • Hole: a bond missing an electron
  • P⁺ B⁻ Dopant atoms that gave or took one electron

Pick phosphorus or boron, then click an atom to swap it in (or use “Add one”). Click it again to swap it back.

Pure germanium

Free electrons
1
Holes
1
Current
None: switch the battery on

Every outer electron is locked in a bond, so there’s almost nothing free to carry a current. Germanium is a little different: its bonds are weaker, so room-temperature warmth alone frees a few electrons, leaving holes behind. That gives a small trickle of current even when pure.

Where doping matters

  • Every chip

    A computer chip holds billions of tiny switches called transistors. Each is a pattern of n-type and p-type silicon, made by doping different areas.

  • Solar cells

    A solar panel is a sheet of n-type silicon on p-type silicon. Light frees electrons near the join, and the join pushes them one way: a current.

  • Germanium came first

    The first transistor, built in 1947, was made of germanium. Silicon took over because its bonds are stronger (a band gap of 1.12 eV against 0.66), so it keeps working when it gets hot.

The crystal is drawn flat: really each atom bonds to four neighbours in 3D, as in diamond. Doping is hugely exaggerated: chips use about one dopant atom per million atoms or fewer. Carrier speeds use room temperature mobilities (germanium: electrons 3,900, holes 1,900 cm²/V·s; Sze, Physics of Semiconductor Devices). The meter shows current in relative units.

Keep exploring

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