Hafnium
Hafnium is a chemical element with symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1923, making it the penultimate stable element to be discovered (rhenium was identified two years later).
At a glance
- Atomic number
- 72
- Atomic mass
- 178.492 u
- Phase
- Solid
- Density
- 13.31 g/cm³
- Melting point
- 2,506 K
- Boiling point
- 4,876 K
- First ionization energy
- 658.5 kJ/mol
- Electronegativity
- 1.3
- Electron affinity
- 17.18 kJ/mol
- Molar heat capacity
- 25.73 J/(mol·K)
- Period
- 6
- Appearance
- steel gray
Conditions and isotopes affect measured properties. Some properties of short-lived elements are predicted. Electronegativity uses the Pauling scale.
Hafnium’s orbitals use a hydrogen-like approximation. Every orbital of each visible subshell is shown: in Shapes as the surface holding half its probability, with light and dark shades for opposite signs of the wavefunction; in Cloud as dots where its electrons are likely to be. Sizes are stepped by shell, like the Shell model.
54 is the [Xe] core total across five shells.
Preparing the orbital view…
72 protons108 neutrons
Hafnium-180: its most common form in nature, or its longest-lived if it has none. The nucleus is drawn far too big: it’s about 100,000 times smaller than the atom.
Turn up the heat
A step of 1 K is the same size as 1 °C, so the two scales are always 273.15 apart. Fahrenheit is different: its degrees are smaller and it starts elsewhere, so water freezes at 273.15 K, 0 °C and 32 °F.25 °C · 77 °FSolid
At this temperature, hafnium is a solid.
At normal atmospheric pressure (1 atm). The temperature scale is logarithmic. The particle box is schematic: real samples hold vastly more atoms, and spacing and speeds are not to scale.
Pull the electrons off
HfNeutral atom · no charge
A neutral hafnium atom. Removing its first electron takes 659 kJ/mol.
Hafnium’s outer shell holds 2 electrons. Electron 3 is the first from an inner shell: it sits closer to the nucleus with less shielding, so removing it takes 1.5× as much energy as the one before. Each dashed line on the chart marks another jump, into a shell even closer to the nucleus.
What does this tell us?
- The jump after hafnium’s outer electrons is small (×1.5), because the electrons in the shell below have similar energies. That’s typical of transition metals, and it’s why many of them, such as iron (Fe²⁺ and Fe³⁺), can form more than one kind of ion.
- Within a shell the steps rise gently. Each electron removed leaves fewer electrons pushing the others away, while the nucleus pulls just as hard, so the next one is held a little more tightly.
Show the values as a table
| Electron | Shell | Energy (kJ/mol) | × previous | Value |
|---|---|---|---|---|
| 1 | 6 | 659 | – | Measured |
| 2 | 6 | 1,410 | 2.1 | Calculated |
| 3 | 5 | 2,176 | 1.5 | Calculated |
| 4 | 5 | 3,220 | 1.5 | Estimated |
| 5 | 5 | 6,597 | 2 | Estimated |
| 6 | 5 | 9,456 | 1.4 | Calculated |
| 7 | 5 | 11,385 | 1.2 | Calculated |
| 8 | 5 | 13,218 | 1.2 | Calculated |
| 9 | 5 | 15,148 | 1.1 | Calculated |
| 10 | 5 | 18,043 | 1.2 | Calculated |
| 11 | 5 | 20,165 | 1.1 | Calculated |
| 12 | 5 | 22,192 | 1.1 | Calculated |
| 13 | 4 | 26,051 | 1.2 | Calculated |
| 14 | 4 | 29,910 | 1.1 | Calculated |
| 15 | 4 | 32,226 | 1.1 | Calculated |
| 16 | 4 | 34,638 | 1.1 | Calculated |
| 17 | 4 | 38,498 | 1.1 | Calculated |
| 18 | 4 | 42,454 | 1.1 | Calculated |
| 19 | 4 | 46,409 | 1.1 | Calculated |
| 20 | 4 | 50,172 | 1.1 | Calculated |
| 21 | 4 | 54,997 | 1.1 | Calculated |
| 22 | 4 | 58,856 | 1.1 | Calculated |
| 23 | 4 | 62,715 | 1.1 | Calculated |
| 24 | 4 | 66,575 | 1.1 | Calculated |
| 25 | 4 | 70,434 | 1.1 | Calculated |
| 26 | 4 | 74,487 | 1.1 | Calculated |
| 27 | 4 | 96,678 | 1.3 | Calculated |
| 28 | 4 | 101,020 | 1 | Calculated |
| 29 | 4 | 105,555 | 1 | Calculated |
| 30 | 4 | 110,572 | 1 | Calculated |
| 31 | 4 | 115,300 | 1 | Calculated |
| 32 | 4 | 120,124 | 1 | Calculated |
| 33 | 4 | 126,492 | 1.1 | Calculated |
| 34 | 4 | 131,413 | 1 | Calculated |
| 35 | 4 | 136,720 | 1 | Calculated |
| 36 | 4 | 141,544 | 1 | Calculated |
| 37 | 4 | 161,034 | 1.1 | Calculated |
| 38 | 4 | 165,858 | 1 | Calculated |
| 39 | 4 | 171,358 | 1 | Calculated |
| 40 | 4 | 176,279 | 1 | Calculated |
| 41 | 4 | 189,401 | 1.1 | Calculated |
| 42 | 4 | 195,093 | 1 | Calculated |
| 43 | 4 | 208,312 | 1.1 | Calculated |
| 44 | 4 | 214,091 | 1 | Estimated |
| 45 | 3 | 360,952 | 1.7 | Calculated |
| 46 | 3 | 372,240 | 1 | Calculated |
| 47 | 3 | 384,398 | 1 | Calculated |
| 48 | 3 | 397,327 | 1 | Calculated |
| 49 | 3 | 409,677 | 1 | Calculated |
| 50 | 3 | 421,834 | 1 | Calculated |
| 51 | 3 | 441,227 | 1 | Calculated |
| 52 | 3 | 453,771 | 1 | Calculated |
| 53 | 3 | 467,568 | 1 | Calculated |
| 54 | 3 | 480,497 | 1 | Calculated |
| 55 | 3 | 516,197 | 1.1 | Calculated |
| 56 | 3 | 527,582 | 1 | Calculated |
| 57 | 3 | 539,835 | 1 | Calculated |
| 58 | 3 | 551,221 | 1 | Calculated |
| 59 | 3 | 593,288 | 1.1 | Calculated |
| 60 | 3 | 606,314 | 1 | Calculated |
| 61 | 3 | 631,496 | 1 | Calculated |
| 62 | 3 | 643,943 | 1 | Calculated |
| 63 | 2 | 1,416,212 | 2.2 | Calculated |
| 64 | 2 | 1,447,183 | 1 | Calculated |
| 65 | 2 | 1,481,146 | 1 | Calculated |
| 66 | 2 | 1,512,890 | 1 | Calculated |
| 67 | 2 | 1,667,267 | 1.1 | Calculated |
| 68 | 2 | 1,705,861 | 1 | Calculated |
| 69 | 2 | 1,754,103 | 1 | Calculated |
| 70 | 2 | 1,785,202 | 1 | Calculated |
| 71 | 1 | 7,194,517 | 4 | Calculated |
| 72 | 1 | 7,340,382 | 1 | Calculated |
Successive ionization energies of gas-phase atoms and ions from the NIST Atomic Spectra Database. Solid bars are measured; hatched bars were estimated from nearby measurements or calculated from quantum theory, as is usual for highly charged ions. Electrons are taken from the outermost shell first, a simplification: electrons in different subshells of the same shell also differ in energy. On the log scale each gridline is 10 times the one below.
How does it compare?
Density
13.3 g/cm³16th highest of 99
Melting point
2,506 K9th highest of 96
Boiling point
4,876 K8th highest of 97
Electronegativity
1.335th lowest of 96
First ionization energy
659 kJ/mol47th lowest of 99
Elements 1–99 from the reference data; heavier elements are left out because only a few atoms have ever been made, so their bulk properties are predictions. First ionization energies come from NIST. Density uses a logarithmic scale, because gases are around a thousand times less dense than solids; gas densities are at 0 °C and 1 atm. Melting and boiling points are at normal pressure. Everyday temperatures and light sources in the pictures are approximate. Hover over a dot to see the element, or click it to compare.
Keep exploring
Explore the stories, imagery, and reference data in more depth. Properties with no value in the reference are marked unavailable.
- HafniumRoyal Society of Chemistry
- HafniumWikipedia
- Quantum numbers and electron configurationsPurdue
- Hydrogenic wavefunctionsNIST
- Ionization energiesNIST Atomic Spectra Database