72HfHafnium178.492[Xe] 4f¹⁴ 5d² 6s²
transition metal

Hafnium

Hafnium is a chemical element with symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1923, making it the penultimate stable element to be discovered (rhenium was identified two years later).

Electronic structure

A stylized shell model. Electrons are quantum objects, not particles following these literal paths. Sizes and motion are illustrative.

Electrons by shell
Electron configuration
4f14
5d2
6s2

54 is the [Xe] core total across five shells.

Properties

At a glance

Atomic number
72
Atomic mass
178.492 u
Phase
Solid
Density
13.31 g/cm³
Melting point
2,506 K
Boiling point
4,876 K
First ionization energy
658.5 kJ/mol
Electronegativity
1.3
Electron affinity
17.18 kJ/mol
Molar heat capacity
25.73 J/(mol·K)
Period
6
Appearance
steel gray

Conditions and isotopes affect measured properties. Some properties of short-lived elements are predicted. Electronegativity uses the Pauling scale.

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