92UUranium238.028913[Rn] 5f³ 6d¹ 7s²
actinide

Uranium

Uranium is a chemical element with symbol U and atomic number 92. It is a silvery-white metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons.

Properties

At a glance

Atomic number
92
Atomic mass
238.028913 u
Phase
Solid
Density
19.1 g/cm³
Melting point
1,405.3 K
Boiling point
4,404 K
First ionization energy
597.6 kJ/mol
Electronegativity
1.38
Electron affinity
50.94 kJ/mol
Molar heat capacity
27.665 J/(mol·K)
Period
7
Appearance
Unavailable

Conditions and isotopes affect measured properties. Some properties of short-lived elements are predicted. Electronegativity uses the Pauling scale.

Electronic structure

Uranium’s orbitals use a hydrogen-like approximation. Every orbital of each visible subshell is shown: in Shapes as the surface holding half its probability, with light and dark shades for opposite signs of the wavefunction; in Cloud as dots where its electrons are likely to be. Sizes are stepped by shell, like the Shell model.

Electrons by shell
Electron configuration

86 is the [Rn] core total across six shells.

Preparing the orbital view…

92 protons146 neutrons

Uranium-238: its most common form in nature, or its longest-lived if it has none. The nucleus is drawn far too big: it’s about 100,000 times smaller than the atom.

States of matter

Turn up the heat

298 KK stands for kelvin, the temperature scale used in science. It starts at absolute zero (0 K), the coldest temperature possible, so it has no negative numbers and no degree sign.

A step of 1 K is the same size as 1 °C, so the two scales are always 273.15 apart. Fahrenheit is different: its degrees are smaller and it starts elsewhere, so water freezes at 273.15 K, 0 °C and 32 °F.
25 °C · 77 °F
Solid

At this temperature, uranium is a solid.

At normal atmospheric pressure (1 atm). The temperature scale is logarithmic. The particle box is schematic: real samples hold vastly more atoms, and spacing and speeds are not to scale.

Ionization energy

Pull the electrons off

U

UNeutral atom · no charge

A neutral uranium atom. Removing its first electron takes 598 kJ/mol.

Uranium’s outer shell holds 2 electrons. Electron 3 is the first from an inner shell: it sits closer to the nucleus with less shielding, so removing it takes 1.7× as much energy as the one before. Each dashed line on the chart marks another jump, into a shell even closer to the nucleus.

Shell 1Shell 2Shell 3Shell 4Shell 5Shell 6Shell 7MeasuredEstimated or calculatedEnergy in kJ/molkJ/mol (kilojoules per mole) is the energy to remove that electron from every atom in a mole of them: about 602 sextillion (6.02 × 10²³) atoms. For a single atom, divide by 96.485 to get electronvolts (eV). Uranium’s first electron takes about 6.2 eV.
1001,00010,000100,0001,000,00010,000,000100,000,000Shell 5Shell 4Shell 3×1.7×1.1×1.1×1.6×2.1×3.9151015202530354045505560657075808590
Show the values as a table
ElectronShellEnergy (kJ/mol)× previousValue
17598–Measured
271,1191.9Measured
361,9101.7Measured
463,5411.9Measured
564,4381.3Calculated
665,9821.3Estimated
768,5871.4Calculated
869,7451.1Calculated
9611,1921.1Calculated
10612,4371.1Calculated
11615,2451.2Calculated
12516,6921.1Calculated
13520,2621.2Calculated
14521,9021.1Calculated
15531,1651.4Calculated
16533,5771.1Calculated
17536,1821.1Calculated
18538,7871.1Calculated
19541,5851.1Calculated
20544,1901.1Calculated
21547,9531.1Calculated
22550,6551.1Calculated
23553,7421.1Calculated
24556,4441.1Calculated
25570,4341.2Calculated
26574,2941.1Calculated
27577,1881Calculated
28581,0481.1Calculated
29589,7311.1Calculated
30593,5911Calculated
315103,2391.1Calculated
325107,0991Calculated
334116,7471.1Calculated
344124,4661.1Calculated
354132,1851.1Calculated
364138,9391.1Calculated
374146,6581.1Calculated
384153,4121Calculated
394161,1311.1Calculated
404168,8491Calculated
414176,5681Calculated
424184,2871Calculated
434192,0061Calculated
444199,7251Calculated
454206,4791Calculated
464214,1971Calculated
474248,7391.2Calculated
484255,3001Calculated
494262,2471Calculated
504269,5801Calculated
514276,6231Calculated
524283,4741Calculated
534296,4991Calculated
544303,6391Calculated
554311,4551Calculated
564318,4981Calculated
574347,5401.1Calculated
584354,5841Calculated
594362,1091Calculated
604369,2491Calculated
614406,5891.1Calculated
624414,7901Calculated
634435,4381Calculated
644443,6401Estimated
653713,3161.6Calculated
663728,4641Calculated
673745,8321Calculated
683763,1991Calculated
693780,5661Calculated
703796,9691Calculated
713834,5981Calculated
723851,9651Calculated
733871,2631Calculated
743888,6301Calculated
753937,8371.1Calculated
763952,3101Calculated
773968,7131Calculated
783984,1501Calculated
7931,100,8981.1Calculated
8031,119,2301Calculated
8131,156,8591Calculated
8231,173,2621Calculated
8322,437,2192.1Calculated
8422,477,7431Calculated
8522,523,0911Calculated
8622,565,5451Calculated
8722,996,8341.2Calculated
8823,052,7961Calculated
8923,126,1251Calculated
9023,168,2411Calculated
91112,501,5953.9Calculated
92112,718,3301Calculated

Successive ionization energies of gas-phase atoms and ions from the NIST Atomic Spectra Database. Solid bars are measured; hatched bars were estimated from nearby measurements or calculated from quantum theory, as is usual for highly charged ions. Electrons are taken from the outermost shell first, a simplification: electrons in different subshells of the same shell also differ in energy. On the log scale each gridline is 10 times the one below.

Radioactive decay

Watching atoms decay

Uranium-238 halves so slowly that about half of what the Earth formed with is still here. Every atom that does decay sets off a relay of unstable atoms that only stops when it reaches lead.

Half of any sample of U-238 decays every 4.47 billion years, turning into Th-234.

U-238 · 100 leftTurned into Th-234 · 0
100%50%25%12.5%0123456

Half-lives passed (1 half-life = 4.47 billion years)

No time passed · 0 half-lives · 100 of 100 atoms left

Each atom decays at a random moment, so no one can say which will go next, but about half of whatever is left goes in every half-life. The dashed curve is the prediction; the solid line is this sample. The new Th-234 atoms decay too, on their own schedule, which the chain below follows.

From U-238 to stable Pb-206: 14 steps

  1. U-238Uranium4.5 billion yearsαdecays by alpha
  2. Th-234Thorium24 daysβdecays by beta
  3. Pa-234mProtactinium1.2 minutesβdecays by beta
  4. U-234Uranium250,000 yearsαdecays by alpha
  5. Th-230Thorium75,000 yearsαdecays by alpha
  6. Ra-226Radium1,600 yearsαdecays by alpha
  7. Rn-222Radon3.8 daysαdecays by alpha
  8. Po-218Polonium3.1 minutesαdecays by alpha
  9. Pb-214Lead27 minutesβdecays by beta
  10. Bi-214Bismuth20 minutesβdecays by beta
  11. Po-214Polonium160 microsecondsαdecays by alpha
  12. Pb-210Lead22 yearsβdecays by beta
  13. Bi-210Bismuth5 daysβdecays by beta
  14. Po-210Polonium140 daysαdecays by alpha
  15. Pb-206Leadstable

Arrows show how each atom decays: α gives off an alpha particle (2 protons and 2 neutrons), β turns a neutron into a proton, γ gives off a gamma ray.

Half-lives and decay modes from the IAEA Live Chart of Nuclides (evaluated ENSDF data). The chain follows each atom’s most common decay; a few steps have rare side branches.

Nuclear fission

Splitting the atom

A uranium-235 nucleus that catches a slow neutron can split in two, releasing energy and 2 or 3 new neutrons. If those neutrons split more nuclei, the process feeds itself: a chain reaction. It’s what powers nuclear power stations.

One split, step by step

1. A slow neutron approaches

A neutron, with no electric charge, drifts towards a uranium-235 nucleus: 92 protons (red) and 143 neutrons (grey).

Proton NeutronDrag to rotate

Where the energy comes from: E = mc²

Weigh the neutron and the uranium atom, then weigh everything that comes out. Masses are in atomic mass units (u), about the mass of one proton.

  • Neutron1.008665 u
  • Uranium-235235.043928 u
On the scale236.052593 ua neutron and a uranium-235 atom

Every particle counted and weighed. Now split it and weigh the pieces.

Split every atom in 1 kg of uranium-235 this way and just 0.79 g of mass disappears, less than a paper clip. That’s about 71 trillion joules, as much as burning about 3,000 tonnes of coal.

The chain reaction

Fire a neutron into the fuel. Add control rods to soak up neutrons, or change how much of the fuel is uranium-235, and try to keep the reaction steady, like a reactor operator.

Fire a neutron to start.

Splits
0
Neutrons flying
0
Uranium-235 left
0

A toy model: a real reactor holds billions of billions of atoms, and water or graphite slows the neutrons so uranium-235 can catch them. Natural uranium is only 0.7% uranium-235; power-station fuel is enriched to a few percent. Barium-141 and krypton-92 are one common pair of fragments among many. Atomic masses from the 2020 Atomic Mass Evaluation (IAEA). Averaged over all the ways it can split, and counting energy the fragments give off later, a fission releases about 200 MeV. Coal taken as 24 MJ/kg.

Compared with other elements

How does it compare?

UraniumOther actinidesOther elements

Density

19.1 g/cm³9th highest of 99

U

Melting point

1,405 K39th highest of 96

U

Boiling point

4,404 K13th highest of 97

U

Electronegativity

1.3840th lowest of 96

U

First ionization energy

598 kJ/mol34th lowest of 99

U

Elements 1–99 from the reference data; heavier elements are left out because only a few atoms have ever been made, so their bulk properties are predictions. First ionization energies come from NIST. Density uses a logarithmic scale, because gases are around a thousand times less dense than solids; gas densities are at 0 °C and 1 atm. Melting and boiling points are at normal pressure. Everyday temperatures and light sources in the pictures are approximate. Hover over a dot to see the element, or click it to compare.

Keep exploring

Explore the stories, imagery, and reference data in more depth. Properties with no value in the reference are marked unavailable.