90ThThorium232.03774[Rn] 6d² 7s²
actinide

Thorium

Thorium is a chemical element with symbol Th and atomic number 90. A radioactive actinide metal, thorium is one of only two significantly radioactive elements that still occur naturally in large quantities as a primordial element (the other being uranium). It was discovered in 1828 by the Norwegian Reverend and amateur mineralogist Morten Thrane Esmark and identified by the Swedish chemist Jöns Jakob Berzelius, who named it after Thor, the Norse god of thunder.

Properties

At a glance

Atomic number
90
Atomic mass
232.03774 u
Phase
Solid
Density
11.724 g/cm³
Melting point
2,023 K
Boiling point
5,061 K
First ionization energy
608.5 kJ/mol
Electronegativity
1.3
Electron affinity
112.72 kJ/mol
Molar heat capacity
26.23 J/(mol·K)
Period
7
Appearance
silvery, often with black tarnish

Conditions and isotopes affect measured properties. Some properties of short-lived elements are predicted. Electronegativity uses the Pauling scale.

Electronic structure

Thorium’s orbitals use a hydrogen-like approximation. Every orbital of each visible subshell is shown: in Shapes as the surface holding half its probability, with light and dark shades for opposite signs of the wavefunction; in Cloud as dots where its electrons are likely to be. Sizes are stepped by shell, like the Shell model.

Electrons by shell
Electron configuration

86 is the [Rn] core total across six shells.

Preparing the orbital view…

90 protons142 neutrons

Thorium-232: its most common form in nature, or its longest-lived if it has none. The nucleus is drawn far too big: it’s about 100,000 times smaller than the atom.

States of matter

Turn up the heat

298 KK stands for kelvin, the temperature scale used in science. It starts at absolute zero (0 K), the coldest temperature possible, so it has no negative numbers and no degree sign.

A step of 1 K is the same size as 1 °C, so the two scales are always 273.15 apart. Fahrenheit is different: its degrees are smaller and it starts elsewhere, so water freezes at 273.15 K, 0 °C and 32 °F.
25 °C · 77 °F
Solid

At this temperature, thorium is a solid.

At normal atmospheric pressure (1 atm). The temperature scale is logarithmic. The particle box is schematic: real samples hold vastly more atoms, and spacing and speeds are not to scale.

Ionization energy

Pull the electrons off

Th

ThNeutral atom · no charge

A neutral thorium atom. Removing its first electron takes 609 kJ/mol.

Thorium’s outer shell holds 2 electrons. Electron 3 is the first from an inner shell: it sits closer to the nucleus with less shielding, so removing it takes 1.5× as much energy as the one before. Each dashed line on the chart marks another jump, into a shell even closer to the nucleus.

Shell 1Shell 2Shell 3Shell 4Shell 5Shell 6Shell 7MeasuredEstimated or calculatedEnergy in kJ/molkJ/mol (kilojoules per mole) is the energy to remove that electron from every atom in a mole of them: about 602 sextillion (6.02 × 10²³) atoms. For a single atom, divide by 96.485 to get electronvolts (eV). Thorium’s first electron takes about 6.3 eV.
1001,00010,000100,0001,000,00010,000,000100,000,000Shell 6Shell 5Shell 4Shell 3×1.5×1.4×1.1×1.6×2.1×4151015202530354045505560657075808590
Show the values as a table
ElectronShellEnergy (kJ/mol)× previousValue
17609–Measured
271,1681.9Measured
361,7681.5Estimated
462,7641.6Measured
565,5962Calculated
666,6671.2Calculated
767,9121.2Calculated
869,1661.2Calculated
9611,3851.2Calculated
10612,8331.1Calculated
11615,9201.2Calculated
12617,4641.1Calculated
13525,2791.4Calculated
14527,4981.1Calculated
15529,9101.1Calculated
16532,4191.1Calculated
17534,9281.1Calculated
18537,5331.1Calculated
19540,9101.1Calculated
20543,5151.1Calculated
21546,3131.1Calculated
22549,0151.1Calculated
23562,7151.3Calculated
24565,6101Calculated
25569,4691.1Calculated
26572,3641Calculated
27580,0831.1Calculated
28583,9421Calculated
29593,5911.1Calculated
30597,4501Calculated
314105,1691.1Calculated
324111,9231.1Calculated
334119,6421.1Calculated
344126,3961.1Calculated
354133,1501.1Calculated
364140,8691.1Calculated
374147,6231Calculated
384154,3771Calculated
394162,0951Calculated
404169,8141Calculated
414176,5681Calculated
424184,2871Calculated
434191,0411Calculated
444198,7601Calculated
454230,6001.2Calculated
464236,8711Calculated
474243,5291Calculated
484250,6691Calculated
494257,5191Calculated
504264,0801Calculated
514276,3341Calculated
524283,1841Calculated
534290,7101Calculated
544297,7541Calculated
554325,6381.1Calculated
564332,3921Calculated
574339,8211Calculated
584346,6721Calculated
594380,4421.1Calculated
604388,3531Calculated
614408,1331.1Calculated
624416,1411Estimated
633672,6961.6Calculated
643687,9401Calculated
653704,2461Calculated
663721,7101Calculated
673738,1131Calculated
683753,5501Calculated
693789,2501Calculated
703805,6531Calculated
713824,9501Calculated
723841,3521Calculated
733889,5951.1Calculated
743904,0681Calculated
753920,4701Calculated
763934,9431Calculated
7731,041,0771.1Calculated
7831,058,4441Calculated
7931,094,1441Calculated
8031,110,5461Calculated
8122,321,4372.1Calculated
8222,361,9611Calculated
8322,406,3441Calculated
8422,446,8681Calculated
8522,837,6341.2Calculated
8622,891,6651Calculated
8722,960,1701Calculated
8823,002,8941Calculated
89111,876,4764Calculated
90112,084,8171Calculated

Successive ionization energies of gas-phase atoms and ions from the NIST Atomic Spectra Database. Solid bars are measured; hatched bars were estimated from nearby measurements or calculated from quantum theory, as is usual for highly charged ions. Electrons are taken from the outermost shell first, a simplification: electrons in different subshells of the same shell also differ in energy. On the log scale each gridline is 10 times the one below.

Compared with other elements

How does it compare?

ThoriumOther actinidesOther elements

Density

11.7 g/cm³22nd highest of 99

Th

Melting point

2,023 K17th highest of 96

Th

Boiling point

5,061 K5th highest of 97

Th

Electronegativity

1.334th lowest of 96

Th

First ionization energy

609 kJ/mol40th lowest of 99

Th

Elements 1–99 from the reference data; heavier elements are left out because only a few atoms have ever been made, so their bulk properties are predictions. First ionization energies come from NIST. Density uses a logarithmic scale, because gases are around a thousand times less dense than solids; gas densities are at 0 °C and 1 atm. Melting and boiling points are at normal pressure. Everyday temperatures and light sources in the pictures are approximate. Hover over a dot to see the element, or click it to compare.

Keep exploring

Explore the stories, imagery, and reference data in more depth. Properties with no value in the reference are marked unavailable.